Dose response of Fricke Gel dosimeters with distinct indicators
DOI:
https://doi.org/10.15392/2319-0612.2024.2599Keywords:
dosimetry, Fricke Gel, gamma radiation, indicatorsAbstract
Fricke solution, composed of ferrous ammonium sulfate in an aqueous solution of sulfuric acid, is used as a chemical dosimeter for gamma rays, X-rays and high energy electrons. The three-dimensional dosimetry has several applications, such as in radiotherapy procedures, imaging diagnosis techniques and internal dosimetry. In this work, the response of Fricke gel dosimeter with two types of indicator was compared. Sodium thiocyanate, a salt not used in dosimetry, and xylenol orange, a well-established indicator, were analyzed as indicators. The studies were performed in a cobalt-60 source. Dosimetric responses of Fricke gel with distinct indicators differ in their sensitivity, that is, the addition of sodium thiocyanate to the gel shifted the saturation point of the gel to an absorbed dose of approximately 300 Gy, while the Fricke gel with xylenol orange presents a saturation of around 30 Gy.
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[1] ICRU. INTERNATIONAL COMISSION ON RADIATION UNITIS. Dosimetry Systems for Use in Radiation Processing. Report 80, p.1–99, 2008.
[2] ISO/ASTM. INTERNATIONAL ORGANIZATION FOR STANDARDIZATION/AMERICAN SOCIETY FOR TESTING AND MATERIALS. Standard Practice for Using the Fricke Dosimetry System. ISO/ASTM 51707:2015(E), 2015.
[3] SCHREINER, L. J. Review of Fricke gel dosimeters. Journal of Physics: Conference Series, v. 3, p. 9–21, 2004. DOI: https://doi.org/10.1088/1742-6596/3/1/003
[4] GORE, J. C.; KANG, Y. S.; SCHULZ, R. J. Measurement of radiation dose distributions by nuclear magnetic resonance (NMR) imaging. Physics in Medicine and Biology, v. 29, p.1189–1197, 1984. DOI: https://doi.org/10.1088/0031-9155/29/10/002
[5] SANTOS, A. M .M.; SEBASTIÃO, R. C. O.; MESQUITA, A. Z.; ALONSO, T. C.; MANTUANO, A.; FONSECA, T. C. F. Dose response assessment of conventional Fricke: a relationship between UV-Visible and nuclear magnetic resonance techniques. Brazilian Journal of Radiation sciences, v.11, p.1–13, 2023. DOI: https://doi.org/10.15392/2319-0612.2023.2194
[6] SANTOS, A.M.M.; MESQUITA, A.Z.; SEBASTIÃO, R.C.O.; FONSECA, T.C.F. Feasibility of new polymeric matrices in the production of ferrous sulphate dosimeters. Applied Radiation and Isotopes, v. 214, p.1–11, 2024. DOI: https://doi.org/10.1016/j.apradiso.2024.111526
[7] CHU, K.C., JORDAN, K.J., BATTISTA, J.J., VAN Dyk, J., RUTT, B.K.. Polyvinyl alcohol–Fricke hydrogel and cryogel: two new gel dosimetry systems with low Fe3+ diffusion. Phys. Med. Biol. v.45, p.955–969, 2000. DOI: https://doi.org/10.1088/0031-9155/45/4/311
[8] IBBOTT, G. S. Applications of gel dosimetry. Journal of Physics: Conference Series, v.3, p.58–77, 2004. DOI: https://doi.org/10.1088/1742-6596/3/1/007
[9] ATTIX, F.H. Introduction to Radiological Physics and Radiation Dosimetry. WILEY-VCH, Weinheim, 2004.
[10] BALDOCK, C. Historical Overview of the Development of Gel Dosimetry: Another Personal Perspective. Journal of Physics: Conference Series, v. 164, p. 1–9, 2009. DOI: https://doi.org/10.1088/1742-6596/164/1/012002
[11] ALVES, A.V.S.; ALMEIDA, W.S.; SUSSUCHIB, E.M.; LAZZERIC, L.; D'ERRICOC, F.; SOUZA, S.O. Investigation of chelating agents/ligands for Fricke gel dosimeters. Radiation Physics and Chemistry, v. 150, p. 151–156, 2018. DOI: https://doi.org/10.1016/j.radphyschem.2018.04.031
[12] RAE, W.I.D., WILLEMSE, C.A., LÖTTER, G., ENGELBRECHT, J.S., SWARTS, J.C. Chelator effect on ion diffusion in ferrous-sulfate-doped gelatin gel dosimeters as analyzed by MRI. Med. Phys. v.23, p.15–23, 1995. DOI: https://doi.org/10.1118/1.597787
[13] OLSSON, L.E., Appleby, A., Sommer, J. A New Dosimeter Based on Ferrous Sulphate Solution and Agarose Gel. Appl. Radiat. Isot., v.42, p.1081–1086, 1991. DOI: https://doi.org/10.1016/0883-2889(91)90015-S
[14] SCOTTI, M., AROSIO, P., BRAMBILLA, E., GALLO, S., LENARDI, C., LOCARNO, S., ORSINI, F., PIGNOLI, E., PEDICONE, L., VERONESE, L. How Xylenol Orange and Ferrous Ammonium Sulphate Influence the Dosimetric Properties of PVA–GTA Fricke Gel Dosimeters: A Spectrophotometric Study. Gels, v.8, p.1–17, 2022. DOI: https://doi.org/10.3390/gels8040204
[15] BOASE, Nathan RB et al. Xylenol orange functionalised polymers to overcome diffusion in Fricke gel radiation dosimeters. Reactive and Functional Polymers, v.132, p.81–88, 2018. DOI: https://doi.org/10.1016/j.reactfunctpolym.2018.09.011
[16] LEMOS, V. A.; SANTOS, L. N.; BEZERRA, M. A. Determination of cobalt and manganese in food seasonings by flame atomic absorption spectrometry after preconcentration with 2-hydroxyacetophenone-functionalized polyurethane foam. Journal of Food Composition and Analysis, v. 23, p. 277–281, 2010. DOI: https://doi.org/10.1016/j.jfca.2009.11.004
[17] National Center for Biotechnology Information, 2024. PubChem Compound Summary for CID 57350048, Iron(3+);hexathiocyanate. Retrieved Decembre 29, from https://pubchem.ncbi.nlm.nih.gov/compound/57350048 .
[18] OZUTSUMI, K., KURIHARA, M., KAWASHIMA, T., 1993. Structure of iron(III) ion and its complexation with thiocyanate ion in N,N-dimethylformamide. Talanta, v.40, p.599–607. DOI: https://doi.org/10.1016/0039-9140(93)80264-R
[19] SOUZA, V.L.B.; SANTOS, C.D.A.; RODRIGUES, K. R .G.; CUNHA, M.S.; FIGUEIREDO, M.D.C.; MELO, R.T. Viability of the Fricke dosemeter doped with methylene blue. V Congresso Brasileiro de Metrologia, 2009.
[20] PARWAIE, W., GERAILY, G., SHIRAZI, A., SHAKERI, A., MASSUMI, H., FARZIN, M. Analysis of the ferrous benzoic methylthymol-blue gel dosimeter in low-dose-level. measurements. Radiation Physics and Chemistry, v. 173, p. 108943, 2020. DOI: https://doi.org/10.1016/j.radphyschem.2020.108943
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