Elementary characterization of metals in lipsticks by EDXRF

Catarina Alzira Montenegro Peddis Torres; Sergei Anatolyevich Paschuk; Danielle Cristine Narloch; Janine Nicolosi Corrêa

doi:10.15392/bjrs.v9i1A.1562

Autores

Catarina Alzira Montenegro Peddis Torres Federal University of Technology - Paraná, UTFPR https://orcid.org/0000-0001-5641-5107 (não autenticado)
Sergei Anatolyevich Paschuk Federal University of Technology - Paraná, UTFPR https://orcid.org/0000-0001-5125-0163 (não autenticado)
Danielle Cristine Narloch Federal University of Technology - Paraná, UTFPR https://orcid.org/0000-0003-2644-0453 (não autenticado)
Janine Nicolosi Corrêa ederal University of Technology - Paraná, UTFPR https://orcid.org/0000-0001-9692-7182 (não autenticado)

DOI:

https://doi.org/10.15392/bjrs.v9i1A.1562

Palavras-chave:

Lipsticks, Heavy metals, EDXRF

Resumo

Usually classified as cosmetic consumer products, makeups usually contain significant quantities of colorants, which may contain toxic and heavy metals, such as Hg, Cd, As, Cr, Tl, and Pb. According the Health Regulatory Agency (ANVISA), lipsticks are classified as low health risk, grade 1. However, similar makeups for the children are classified as grade 2, high risk, and within this category there is no cosmetic product for embellishment. Many metals, present in the colorants, can cross the mucous membranes and skin barrier and could be absorbed into the blood system, which can cause systemic damage to internal organs. Many chemical components present in the lipsticks, such as Al, Pb, Cd, Br, Cu, Zr, Cr, Hg, TiO₂in nanoparticulate form, could be considered as potentially toxic. Present work was undertaken in order to study the presence of mentioned above metals in the samples of commercial lipsticks. The metals characterization and elementary identification was performed using EDXRF technique. This method allows to perform the qualitative and quantitative analysis by means of the characteristic X-rays spectra emitted by the elements present in studied samples. The experimental setup was based on mini X-ray tube with Ag target and detector (AMPTEK). The partial results of the study revealed that the lipstick samples revealed the presence of Mg, Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Zn, Br, Rb, which suggest that prolonged and constant use of such cosmetics may constitute a potential threat to the health especially in the case of children.

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